Synthesis of Multi-Heterocyclic Compounds Contain Phosphorus
Presentation Type
Poster Presentation
Mentor/Supervising Professor Name
Duffy, Matthew
Presentation Location
On Campus
Description
For my research project, I will be using phosphorus compounds such as 5-Phenyl-5H-benzo[b]phosphindole and 2,2’-Dibromobiphenyl to synthesize my compound. Because my compound has not been made yet, I will be taking information from various sources and combining them to develop a step-by-step procedure. After my compound is synthesized, I will be using reagents to add on groups using Diels-Alder reactions.
After my compound is synthesized, I will be looking into adding heterocyclic rings to the compound all around. I will be experimenting with the use of tetraphenylcyclopentadienone and 1,2-bis(4-butylphenyl)ethyne to give hexaphenylbenzene.
Synthesis of Multi-Heterocyclic Compounds Contain Phosphorus
On Campus
For my research project, I will be using phosphorus compounds such as 5-Phenyl-5H-benzo[b]phosphindole and 2,2’-Dibromobiphenyl to synthesize my compound. Because my compound has not been made yet, I will be taking information from various sources and combining them to develop a step-by-step procedure. After my compound is synthesized, I will be using reagents to add on groups using Diels-Alder reactions.
After my compound is synthesized, I will be looking into adding heterocyclic rings to the compound all around. I will be experimenting with the use of tetraphenylcyclopentadienone and 1,2-bis(4-butylphenyl)ethyne to give hexaphenylbenzene.
Comments
“N-Butyllithium.” Wikipedia, Wikimedia Foundation, 27 Dec. 2022, https://en.wikipedia.org/wiki/N-Butyllithium.
Van Kalkeren, Henri A., et al. “In Situ Phosphine Oxide Reduction: A Catalytic Appel Reaction.” Chemistry - A European Journal, vol. 17, no. 40, 2011, pp. 11290–11295., https://doi.org/10.1002/chem.201101563.
Eisenberger, Patrick, et al. “Mild Electrophilic Trifluoromethylation of Secondary and Primary Aryl- and Alkylphosphines Using Hypervalent Iodine(III)–CF3 Reagents.” Chemical Communications, no. 13, 2008, p. 1575., https://doi.org/10.1039/b801424h.
Setia, Shilpa, et al. “Scholl Reaction of Hexaphenylbenzenes with Hexakis-Alkoxy Substituents.” Liquid Crystals, vol. 46, no. 3, 2018, pp. 430–441., https://doi.org/10.1080/02678292.2018.1508765. Thiemann, Thies, et al. “Cheminform Abstract: Thermal Oxidation of Tetracyclones (2,3,4,5-Tetraarylcyclopentadienones).” ChemInform, vol. 39, no. 35, 2008, https://doi.org/10.1002/chin.200835029.